9/13/2023 0 Comments Diffractometer definitionDirect heaters are non-ambient XRD attachments that either have a sample holder that is placed on a resistance heater (Figure 4, A) or are so-called strip heaters, where the sample is directly placed on a resistively heated heating strip (Figure 4, B). In principal there are two types of heaters: direct heaters and environmental heaters. The investigation of these processes is not only interesting for the scientific community, but also for many technological processes used in industry.Īpplication examples will be given at the end of this article. Some of them are listed below:Īpplication fields: alloys, building materials, drug APIs, catalysts, minerals,…Īpplication fields: alloy, ceramics, polymers,…Īpplication fields: catalysts, zeolites,…Īpplication fields: building materials, pharmaceuticals, food industry,…Īpplication fields: catalysts, refractory materials, alloys,… These parameters result in a variety of material changes that can be investigated in-situ. The most important parameters are listed below: In non-ambient X-ray diffraction the sample is influenced by external parameters during the experiments. So far it has been explained what kind of information can be gained from X-ray diffraction experiments under ambient conditions. But these will not be further discussed here. More sophisticated methods of X-ray diffraction can be used to extract much more information from the samples. Also this effect can be quantified by XRD measurements. Microstrain in the sample also results in peak broadening. This can be used to extract information about the size of the crystallites. Crystallites that are smaller than ~120 nm give broader peaks. Crystallite Size and Strain: The crystallite size of the powder has an influence on the width of the obtained peaks.This can be especially interesting under non-ambient conditions. XRD allows characterizing the dimensions of this unit cell. The smallest building block of such a regular arrangement is the unit cell of the material. Unit Cell Lattice Parameters: As mentioned above crystalline materials are regularly arranged.Quantitative Analysis: If the sample is not a pure substance, but consists of several components, it is also possible to calculate the relative amounts of the individual phases.Comparison of the obtained data with databases results in the identification of the material. This can be seen as the fingerprint of the sample. Qualitative Analysis: Every crystalline material produces a specific diffractogramm.Obtainable information from a diffractogramm: This is a plot of X-ray intensity on the y-axis versus the angle 2θ (2θ is defined as the angle between the incident and the diffracted beam) on the x-axis. The result of the measurement is a so called diffractogramm. As the wavelength in XRD experiments is known and the angles at which constructive interference occurs are measured, the use of the Bragg equation allows determining the distance between the lattice planes of the material. In words this equation can be described as follows: constructive interference occurs only if the path difference (given by 2d sinθ) is a multiple (n=1,2.) of the used wavelength of the X-ray beam. This is summarized in the famous Bragg – Equation: The magnitude of this path length only depends on the distance between the crystal planes and the incident angle of the X-ray beam. The resulting diffracted X-rays therefore have a different optical path length to travel. The incident X-ray beam is scattered at different planes of the material. Due to the crystalline nature, the atoms are arranged periodically. The dots in the graph correspond to the building blocks of a crystalline material. This is schematically shown in the next picture. This means that detectors can read-out a signal only at angles where constructive interference occurs. The scattered X-rays from the sample interfere with each other either constructively or destructively.
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9/13/2023 0 Comments Borderlands season pass 2 reviewGearbox or 2K should confirm the price soon. This content is included with purchase of the. Note: Requires Borderlands 3 on Epic to play. All 4 Multiverse Final Form Cosmetic Packs. Directors Cut content add-on, with details to be announced. We’re assuming the Director’s Cut won’t be the same price as otherwise that means you can get both DLCs for $29.98, 1 cent cheaper than the season pass. Accrued review scores for Handsome Jackpot amount to a solid 72 on Metacritic, with the main complaint being that people wanted more, even after finishing the campaign. Season Pass 2 includes: Designers Cut content add-on, featuring brand new mode Arms Race and an additional skill tree for each Vault Hunter. The Designer’s Cut DLC is currently available for $14.99. may not be appropriate for all ages, or may not be appropriate for viewing at work. Other content included with the DLC involves behind-the-scenes content such as bloopers, cut content, concept art, storyboards, lost maps, and “tons of footage that charts the game’s development.” Director’s Cut will be available as part of Season Pass 2 for $29.99, or it can be purchased individually. Season Pass 1 VS 2 :: Borderlands 3 General Discussions. If players have access to multiple cards, they can pick the one they want active at any time, and the content never expires. The content of the other two cards hasn’t been revealed but they’ll be released throughout the year. The new story campaign and raid boss provide an exciting challenge for. The first card to launch will feature items that honor the franchise’s heroes that didn’t make it. Overall, Borderlands 3 Season Pass 2 is a great addition to the Borderlands 3 experience. Max out the card and you’ll get a “massive” cache of themed cosmetic items, as well as “supremely powerful” gear that will scale to your level. Aggregating review website Metacritic 59 the gave the PlayStation. Once a Vault Card is activated, players level it up by completing a selection of more than 100 daily and weekly challenges. Borderlands 2 was met with critical acclaim. Three Vault Cards will be available to owners of the Director’s Cut DLC. Ensure you get over 10+ unbiased reviews of Borderlands 3 before deciding whether to purchase. Of course, there’ll also be loot to find along the way, as well as teasers, hints, and secrets that relate to the game’s main story. Continue your Borderlands 3 adventure with the Season Pass, featuring exclusive cosmetic items and four story campaign add-ons with new missions and challenges This content is. Quick Review for Borderlands 3: Season Pass 2 from Steam. The missions will take players to new locations on Pandora, Promethea, Eden-6, and Nekrotafeyo. Ava thinks they’re supernatural, and it’s up to you to keep her safe as she investigates the killings for her podcast series. Mysterious deaths have occurred in several places. While it's unlikely that Season Pass 2 will introduce better jokes, the Designer's and Director's Cuts should give Borderlands 3 players a lot more cause to tolerate a few unfunny goofs.There will also be murder mystery missions to solve using a crime scene analysis mechanic. Borderlands' signature style of off-kilter humor, in particular, is beginning to grate with fans. Announced via an official blog post Thursday. Season Pass 2 includes: Designers Cut content add-on, featuring brand new mode Arms Race and an additional skill tree for each Vault Hunter Directors Cut. The enigmatic Arms Race mode should encourage players to come back to the game as well Gearbox has made a big deal about how drastically the mode will change up the core gameplay fans are used to.įans still have a lot of love for the satisfying progression systems and hectic gunplay of Borderlands 3, but there are certainly some aspects in which the series has aged less than gracefully. Borderlands 3 Season Pass 2 has been revealed by Gearbox Software, and it features two big DLC expansions with new Skill Trees and fresh ways to play. Giving each character new progression systems is an excellent way to make a game like Borderlands 3 worth replaying fans should have a lot of fun seeing how the new ability options can help them create their ideal vault hunting build. If Gearbox is indeed trying to go toe-to-toe with Destiny 2, this seems like a solid way to do it. 9/13/2023 0 Comments Everyday tao quotesFor example, a mother asks her daughter if she got into college. But obviously, instead of resolving it, he pushed the conflict off into the future, where it will grow in strength. After telling the lie, the liar believes he’s resolved the conflict in a quick and easy manner. So why does he continue to lie to himself?Ī lie is something that gives the illusion of resolving a conflict. And as he seeks to avoid conflict, he tells himself more lies, his delusions cut him off from more and more knowledge, and as a result, his mind becomes completely fixed and rigid. He protects himself from conflict, but he also cuts himself off from all knowledge that would have helped him overcome his awkwardness. He tells himself that society is full of losers not worth talking to. But if the man acknowledges his awkwardness, he knows he would be conflicted, so he protects himself from the conflict by constructing a delusion. For example, a man, because he’s awkward, has a few bad interactions with others. In other words, no more knowledge can enter the mind. Although the poison can’t enter the glass, no more water can either. The delusion is a self-isolating barrier. The mind wants so badly to protect itself from conflict that it constructs a delusion around itself by telling itself lies. The water represents the mind, the glass represents the delusion, and the poison represents conflict. Imagine a water-filled glass placed upside down on a table. Rigidity occurs when the mind creates a barrier that prevents it from receiving new information. But the water-like sage retains a mind that is formless, unbounded, and constantly learning, lacking rigidity and capable of responding to any situation. But as many children grow older, their minds tend to calcify, they become more rigid, and they stop learning. Nothing but potential lies in front of it, and it does nothing but learn all day. Its mind is still fresh, unjaded, and unconditioned by the world. A child is a great example of formlessness. So the water-like sage must be formless too, but what does it mean to be formless?Ī formless mind is capable of endless, expansive growth. It can become whatever it needs to suit the situation, in cold turning to ice, in heat to vapour. And because it’s formless, water is adaptable. I said that water could be described in many ways, but I think it has one, chief characteristic: it’s formless. In Taoism, this “best man” is referred to as a Sage, and by taking on the qualities of water, the Sage comes close to the Tao. And in one translation of the Tao Te Ching, in Chapter 8, Lao Tzu says, “the best of men is like water.” Water can give life, conform to any container, flow around any obstacle, erode mountains, destroy cities, cleanse, heal, travel to the lowest and highest spots, move effortlessly and efficiently, and transform into ice, water, or vapour depending on the circumstances. In the Tao Te Ching, Lao Tzu compares the Tao to water. 9/13/2023 0 Comments Tibia and fibula surgeryThey will attach these to a rigid frame called an external fixator to hold the bone in place. The surgeon may also use rods placed inside the tibia or pins placed through the bones above and below the fracture. A surgeon may place metal screws and plates on the bone to hold it in the right place, allowing it to heal with minimal long-term damage. In severe cases, surgery may be necessary to make sure the bone heals properly. Treatment of a tibia fracture depends on several factors, including a person’s overall health at the time of the injury, the cause and severity of the injury, and the presence or extent of damage to the soft tissues that surround the tibia. Share on Pinterest A cast, brace, or splint may be used to treat a tibia fracture if surgery is not appropriate. With closed fractures, the bone does not break the skin, though there may still be internal tissue damage. Open fractures are fractures where a broken bone breaks through the skin. When bones are broken, they can either stay under the skin or break through its surface. This model is fully interactive and can be explored with your mouse pad or touchscreen. When the bone fractures into three or more pieces, this is called a comminuted fracture.īelow is a 3-D model of a stable fracture of the tibia. When a twisting movement causes a break, there may be a spiral-shaped fracture of the bone. These fractures are small, thin cracks in the bone. Stress fractures, also called hairline fractures, are common overuse injuries. Surgery is often needed to correct this type of fracture and realign the bones back together. With a displaced fracture, a crack in the bone moves part of the bone so that it is no longer aligned. The broken parts of the tibia line up and maintain their correct position during the healing process. A stable fracture involves a crack in the bone that leaves most of the bone intact and in its normal position. The tibia can have the following types of fracture: Tibia shaft fractures occur below this area. Proximal fractures are those that affect the upper part of the tibia. It may be a transverse fracture, meaning the crack is horizontal across the bone, or oblique, meaning the crack is at an angle. Depending on the cause of the broken bone, the severity and type of fracture may vary. How does Portland Oregon reduce air pollution? Cool air inversions persist, accumulating surface-level air pollution until temperature and weather change allow sunlight to warm the surface air more than the air above. Snow cover and sparse light contribute to these conditions, creating freezing cold surface air. Cool air inversions, or temperature inversions, occur when warm air caps colder air below, preventing the normal dispersion of air pollution in the atmosphere. This is the case for Portland’s most polluted months in November and December. More often, PM2.5 spikes are the result of domestic wood burning and cool air inversions in the winter. The Mosier Creek Fire, which burned east of Hood River in the town of Mosier in August 2020, is an example of a wildfire that caused “unhealthy” PM2.5 pollution levels in Portland. Portland’s PM2.5 pollution tends to be attributable to vehicular emissions, wildfires in the late summer and early fall, and domestic wood burning in the winter months. Limiting the emissions of pollution sources, such as switching to cleaner energy, transitioning to electric vehicles, and cooperating with regional towns and cities, offer an opportunity for reducing ozone despite warming temperatures creating more ideal conditions for its formation. 2 As temperatures continue to rise as a result of climate change, it will be increasingly difficult to manage ozone levels. Portland’s ozone season runs from May through September, when the city experiences an average of 51 days over 80 degrees. Portland, for example, can be adversely affected by Seattle air quality, Bend air quality, or Eugene air quality. Precursor pollutants are largely emitted by vehicles and smoke stacks however, they can also travel hundreds of miles from neighboring cities when carried by wind. Ozone, a secondary pollutant, occurs in the atmosphere when high temperatures (over 84☏) and sunlight (UV radiation) causes pollutants, nitrogen oxides (NO x), and volatile organic compounds (VOCs) to react. While both pollutants share some of the same sources, such as motor vehicles and fossil fuel combustion at industrial complexes, power plants, and factories, they are also unique. Portland’s unhealthy air pollution is a combination of PM2.5 and ozone pollution, two of the most prevalent and dangerous pollutants in the US. Ozone tends to indicate warmer temperatures and increased vehicular traffic, such as during rush hour, though individual sources may vary. When Portland PM2.5 levels are exceedingly high, there is usually a fire burning nearby or domestic wood burning during a cool air inversion. The “main pollutant” indicates which of the six criteria pollutants is present at the riskiest levels (usually PM2.5 or ozone). Monitor Portland air pollution data at the top of this page to stay aware of pollution spikes and health advisories. Meanwhile, ozone, a secondary pollutant, only becomes problematic in the summer, when abundant sunshine and heat create ideal conditions for its formation. Fine particle pollution tends to rise in the winter months with increased household wood burning and pollution-trapping temperature inversions. In Portland, each season brings unique pollution challenges. This is a slip from Portland’s “A” rating in the 2014 to 2016 monitoring period, which experienced less than 1 unhealthy day a year. 1 Due to the frequency of these events, the American Lung Association (ALA) graded Portland a “C” for 24-hour PM2.5 and 24-hour ozone in their 2019 State of the Air report. In the most recent 3-year monitoring period spanning 2016 to 2018, Portland averaged roughly 3 unhealthy pollution days a year. The concerning trend coincides with a growing population and number of vehicles on the road, numerous EPA regulatory rollbacks, warming global temperatures, and more frequent and severe wildfires. Portland air quality has achieved a mean annual air quality index (AQI) rating of “good.” For the last two decades, Portland has achieved air pollution standards set by the Environmental Protection Agency (EPA) for all six criteria pollutants measured in real-time: PM2.5, PM10, ozone, carbon monoxide (CO), nitrogen dioxide (NO 2), and sulphur dioxide (SO 2).ĭespite this success, Portland’s air pollution levels have been climbing since 2016. 9/13/2023 0 Comments Gylt jogarEarn Your Happy Ending: This is possible if you gain all the collectables throughout the game itself.As a result, she completely vanishes along with the dark world and now she turns out to be missing in the real world. The second ending involves Sally letting Emily leave the dark world whilst she stays behind because she couldn't go back home or forgive herself for not being there for her cousin. One ending has Sally leave her cousin behind in the dark town as she continues to put up posters of her as if nothing had even happened. Downer Ending: Both common endings if all collectables aren't gotten.Downer Beginning: Basically how the story begins, with the intro revolving around Sally putting up missing posters of her cousin, Emily around town.Double-Meaning Title: "Gylt" sounds exactly like "guilt", which is what Sally is suffering from due to doing nothing as her cousin Emily was being bullied.Creepy Doll: Some monsters appear as teenage-girl-sized robots with the appearance of an unvarnished porcelain doll.Collection Sidequest: There are a few collectibles, which also affect the kind of ending you would get.By doing nothing to help her, Sally herself is really no different from the bullies who went after Emily. Bystander Syndrome: Hugely Deconstructed.Since it is taller than Sally's and Emily's school. Attack of the 50-Foot Whatever: Helplessness fits this description.Air-Vent Passageway: Sally often has to crawl through the vents to get to the otherwise inacessible rooms (such as one with her first inhaler), which is done with relative ease and comes with neither dust nor noise.Yet, at the same time, she soon learns that Emily had somehow been stuck in this place as well and so now, she must attempt to not only survive but also rescue her from this nightmare. Upon arriving, however, she notices that her town had suddenly turned into a twisted and dangerous version of itself. The player takes on the role of Sally, a schoolgirl who is dealing with the recent disappearance of her cousin Emily, and was putting up "missing" posters of her when she suddenly gets accosted by bullies and takes a route home she is not used to. Following the announcement that Stadia was shutting down, the developers announced a multiplatform release, with the game releasing for Steam, PlayStation 4, PlayStation 5, Xbox One and Xbox Series X|S on July 6, 2023. You can avoid being detected by creatures, you can build strategies to distract them, through sound or visual lures or by attracting them.Gylt is a 3D Survival Horror game, developed by Tequila Works (the creators of Deadlight and The Sexy Brutale) and released on November 19th, 2019 as Google Stadia launch exclusive.Decide to either face the creatures or hide from them, in the same way you’d face or hide your fears.Get to understand the world surrounding and discover the mystery behind Emily’s disappearance.After being chased by a group of bullies, Sally is dragged into a twisted version of her town where her fears and worse memories are presented in a wicked and very real way. Her life is not easy, and it has become even worse since her little cousin Emily disappeared. The story:Live the story of Sally, a little girl living in Bethelwood. The game:GYLT is a narrative adventure game with puzzles, stealth and action, set in a fictional old mining town in the state of Maine. Hide from terrible creatures or confront them as you find your way through the challenges of this wicked world. Set in a creepy and melancholic world, GYLT is an eerie story mixing fantasy and reality in a surrealist place where your nightmares become reality. About This Game Shape your fears… Fear the shapes. Microsoft Windows packages for MySQL 5.6 are available both as a 'full' installer and as a 'web' installer. Migration also supports migrating from earlier versions of MySQL to the latest releases. Dear MySQL users, MySQL Server 5.6.43, a new version of the popular Open Source Database Management System, has been released. 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MySQL Workbench delivers visual tools for creating, executing, and optimizing SQL queries. It includes everything a data modeler needs for creating complex ER models, forward and reverse engineering, and also delivers key features for performing difficult change management and documentation tasks that normally require much time and effort. MySQL Workbench enables a DBA, developer, or data architect to visually design, model, generate, and manage databases. Bitcoin was the largest portion of the reserve assets, though LFG also held reserves in various other stablecoins and cryptocurrencies. As of 7 May, just before UST broke its peg, LFG held reserves of 80,394 bitcoin worth approximately $2.4 billion. Terraform Labs allocated a portion of the money obtained from UST sales to Luna Foundation Guard, to be used as reserves to stabilise the price of UST. In January 2022, the Luna Foundation Guard (LFG) was established as a non-profit based in Singapore, with Do Kwon serving as its director. Terraform Labs raised more than $200 million from investment firms such as Arrington Capital, Coinbase Ventures, Galaxy Digital and Lightspeed Venture Partners. In 2019, Terraform Labs launched its first cryptocurrency token. In 2018, Do Kwon and Daniel Shin (also known as Shin Hyun-sung ) co-founded Terraform Labs in Seoul, South Korea. Mirror Protocol was another project based on the Terra chain, which designed and offered financial derivatives that virtually "mirrored" actual listed stocks. Due to such a high-yielding mechanism of the Anchor Protocol, some critics raised concerns that Kwon's stablecoin model could function like a "ginormous Ponzi scheme". Investors who deposited UST in the Anchor Protocol were receiving a 19.45% yield that was paid out from Terra's reserves. The Anchor Protocol was a lending and borrowing protocol built on the Terra chain. This method uses a two-token system, whereby one token is supposed to remain stable (UST) while the other token (LUNA) is meant to absorb volatility. dollars instead, it was designed to maintain its peg through a complex model called a "burn and mint equilibrium". Luna serves as the primary backing asset for Terra, and is also used as a governance token for users to vote on Terra community proposals. Terra is a group of algorithmic stablecoins, named according to the currencies to which they are pegged-for example, TerraUSD (UST) is pegged to the U.S. The Terra blockchain has a fully-functional ecosystem of decentralized applications (or DApps), such as Anchor, Mirror, and Pylon, which utilised the stable-coin infrastructure of Terra. Several stablecoins are built atop the Terra protocol, including TerraUSD, which was the third largest stablecoin by market capitalisation before its collapse in May 2022. For consensus the Terra blockchain uses a proof-of-stake codesign. Terra is a blockchain that leverages fiat-pegged stablecoins to power a payment system. In May 2022, the Terra blockchain was temporarily halted after the collapse of the stablecoin TerraUSD (UST) and Luna, in an event that wiped out almost $45 billion in market capitalisation within a week. It is most known for its Terra stablecoin and the associated Luna reserve asset cryptocurrency. The project was created in 2018 by Terraform Labs, a startup co-founded by Do Kwon and Daniel Shin. As I’ve journeyed around the globe, I’ve developed my own “system” for recording my various travel experiences.Terra is a blockchain protocol and payment platform used for algorithmic stablecoins. Part of it involves my camera, part a travel journal and part my travel blog. I’m not saying it’s the best way to record the journey, it’s merely the way I do it. You will most certainly see and experience a destination different than I will. You will also have a different preference for how you want to remember it. Or maybe you’re like me and you prefer to sit alone with some awesome noise-cancelling headphones to write with pen to paper. Maybe you’d rather have everything digital and backed up to the cloud. There are so many different methods, which is why there are so many different kinds of travel journals. Don’t look at this list of the best travel journals and best travel journal apps and get overwhelmed.ĭetermine how you want to record your travels and then find the journal or app that fits your needs.įindPenguins is a beautiful travel app that automatically tracks your travels using a combination of your device’s GPS and artificial intelligence. 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9/12/2023 0 Comments Timeless quotes plato loveWhen men speak ill of thee, live so as nobody may believe them.He could not harm me, for I do not think it is permitted that a better man be harmed by a worse.Beauty of style and harmony and grace and good rhythm depend on simplicity.A life without investigation is not worth living.The difficulty, my friends, is not in avoiding death, but in avoiding unrighteousness for that runs faster than death.Character is simply habit long continued.The greatest wealth is to live content with little.Education is teaching our children to desire the right things.
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